Synthesis of Silsesquioxanes Based in [3-(Methacryloxy)propyl]trimethoxysilane Using Methacrylate Monomers as Reactive Solvents

SILVANA ASMUSSEN; SILVANA L. GIUDICESSI; ROSA ERRA-BALSELLS; CLAUDIA I. VALLO

EUROPEAN POLYMER JOURNAL

PERGAMON-ELSEVIER SCIENCE LTD

Lugar: Amsterdam; Año: 2010 vol. 46 p. 1815 - 1823

0014-3057

The polycondensation of (3-methacryloxypropyl)-trimethoxysilane in acidic conditions using different methacrylate monomers as reactive solvents resulted in incompletely condensed methacrylate-functionalized silsesquioxanes with a very large fraction of intramolecular cycles. UV-MALDI-TOF-MS analysis demonstrated that the species present after 2 weeks of reaction at 60 ºC were: T6(OH)2, T7(OH), T8(OH)2, T9(OH), T10(OH)2 and T11(OH). Analysis of samples after 30 months of storage at room temperature revealed the presence of T12(OH)2 and T13(OH) species. The absence of higher molar mass oligómeros after prolonged storage periods is attributed to dilution of the reacting medium, which discourages bimolecular reactions that lead to polymer growth. 29Si NMR spectroscopy showed that the conversion in the polycondensation reaction was in the range 0.91– 0.96. The methacrylate monomers are not involved in the hydrolysis–condensation reactions with MPTMS and therefore can be polymerized by thermal or photochemical means, thereby cross-linking the preformed nanosized cagelike silsesquioxanes. The formulations containing silsesquioxanes showed a markedly reduced content of extractable monomer after photopolymerization, which makes these resins very attractive for dental filling materials.