SMM Behaviour of the Butterfly {Cr III 2 Dy III 2 } Pivalate Complex and Magneto‐structurally Correlated Relaxation Thermal Barrier

MECCHIA ORTIZ, JUAN H.; CABROSI, DAIANA; CARRELLA, LUCA M.; RENTSCHLER, EVA; ALBORÉS, PABLO

CHEMISTRY-A EUROPEAN JOURNAL

WILEY-V C H VERLAG GMBH

Año: 2022

0947-6539

We are reporting the synthesis, single-crystal X-ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII2LnIII2} complexes with Ln= Gd and Dy and the isostructural Y(III) sample. We found an anti-ferromagnetic Cr(III)-Ln(III) exchange interaction, which, as previously observed in related Cr(III)/Ln(III) systems, plays a key role in suppressing quantum tunnelling of magnetization and enhances the SMM performance in the Dy(III) complex. In fact, a pure Orbach relaxation mechanism, with absence of QT regime, is observed with a thermal barrier of 50 cm-1, leading to magnetization hysteresis opening, measured with a commercial magnetometer, up to 3.6 K with a coercive field of 2.9 T. Analysis of SMM behaviour in literature-known butterfly {CrIII2DyIII2} complexes, reveals the existence of a magneto-structural correlation between Ueff, the thermal barrier size, and the mean Cr-Dy bond distances. Moreover, a clear correlation is found for the thermal barrier magnitude and the maximum temperature hysteresis opening and coercive field.