Study of carbon nanotubes and functionalized-carbon nanotubes as substrates for flow injection solid phase extraction associated to inductively coupled plasma with ultrasonic nebulization. Application to Cd monitoring in solid environmental samples.

BELÉN PARODI; MARIANELA SAVIO; LUIS D. MARTINEZ; RAÚL A. GIL; PATRICIA SMICHOWSKI

MICROCHEMICAL JOURNAL

ELSEVIER SCIENCE BV

Año: 2011 p. 225 - 230

0026-265X

A research was performed to evaluate the capabilities of carbon nanotubes (CNTs) and modified CNTs to serve as sorbents for preconcentrating Cd together with on-line ultrasonic nebulization (USN)-inductively coupled plasma optical emission spectrometry (ICPOES). Three different carbon nanotubes sustrates namely, carbon nanotubes (CNTs), oxidized-carbon nanotubes (ox-CNTs) and l-alanine-carbon nanotubes (ala-CNTs) were studied systematically and the main factors influencing the preconcentration and determination of Cd were examined thoroughly. The CNTs evaluated showed dissimilar adsorption behaviors leading to increasing preconcentration factors when used in the proposed on-line solid phase extraction (SPE) system as follows: CNT