INVESTIGADORES
IGLESIAS Rodrigo Alejandro
artículos
Título:
Ion-Transfer Processes Across Liquid/Liquid Interfaces Promoted by Convective Flux
Autor/es:
NATALIA WILKE; RODRIGO A IGLESIAS; SERGIO G CHESNIUK; SERGIO A DASSIE; ANA M BARUZZI
Revista:
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Editorial:
Chemical Society of Japan
Referencias:
Año: 2002 vol. 75 p. 235 - 240
ISSN:
0009-2673
Resumen:
Convective flux produced by stirring either the aqueous or the organic phase is proposed as a mechanistic tool to study the ion-transfer processes at ITIES. The dependence of the voltammetric response on the sweep rate and the rotation frequency was used to differentiate the simple transfer of TEA+ from the assisted transfer of K+ by DB18C6 at a water 1,2-dichloroethane interface.
