INVESTIGADORES
TROIANI Horacio Esteban
artículos
Título:
Fe/SiO2 nanocomposite soft magnetic materials
Autor/es:
HUI; ZHANG; XIAO; WU; GE; BUDNICK; YACAMAN; TROIANI
Revista:
MATERIALS RESEARCH SOCIETY SYMPOSIA PROCEEDINGS
Editorial:
Elsevier
Referencias:
Año: 2002 p. 237 - 242
ISSN:
0272-9172
Resumen:
In an effort to explore new highly resistive soft
magnetic materials, Fe/SiO2 nanocomposite materials have been
synthesized using a wet chemical reaction approach in which the
precursor complex was annealed at various temperatures. The
crystallographic structure, nanostructure, morphology, and magnetic
properties of the synthetic Fe/SiO2 particles were studied by x-ray
diffraction, transmission electron microscopy, and magnetic
measurements. The experimental results show that for this approach, the
α-Fe particles are coated with amorphous silica. The progress of the
reaction, the purity of Fe/SiO2 in the synthetic powder, and the Fe
particle size are highly dependent on the annealing temperature. By
adjusting the annealing temperature, the particle size can be controlled
from approximately 20 nm to 70 nm. For the synthetic nanopowder
obtained by H2 reduction at 400°C, there exists a superparamagnetic
behavior below room temperature; while for the nanopowders obtained by
reduction at higher temperatures, the ferromagnetic behavior is
dominant. Based on these studies, optimum synthesis conditions for
Fe/SiO2 nanocomposites is determined.