INVESTIGADORES
TROIANI Horacio Esteban
artículos
Título:
The bcc-to-fcc phase transformation during dezincification of β-phase Cu-Zn
Autor/es:
TROIANI; PELEGRINA; AHLERS
Revista:
PHILOSOPHICAL MAGAZINE A
Editorial:
Taylor and Francis
Referencias:
Año: 1998 p. 1253 - 1267
ISSN:
0141-8610
Resumen:
β-phase Cu-48at% Zn single-crystal slices with (100)β and
(110)p surface orientations have been dezincified in vacuum at 450 and
600°C for various times, and the resulting surfaces have been studied by
optical microscopy, and also by scanning and transmission electron
microscopy. On dezincification, the β phase becomes unstable and two
different competing nucleation processes occur, one being a coherent
homogeneous nucleation within the β-phase matrix of a non-equilibrium 4H
type of hexagonal structure, and the other a heterogeneous formation of
long straight needles of the fcc α phase, with an interface orientation
given by (211)β parallel to (121)α and a parallelism of the close packed directions [011]β and [111]α within the planes.