Structural and magnetic study of nanostructured (Fe79Mn21)80Cu20 alloy synthesized by ball milling

MIZRAHI; CABRERA; STEWART; TROIANI; COTES; DESIMONI

PHYSICA B - CONDENSED MATTER

ELSEVIER SCIENCE BV

Lugar: Amsterdam; Año: 2004 p. 133 - 136

0921-4526

We have obtained by high-energy ball milling of the powder elements, a nanostructured (Fe79Mn21)80Cu20 FCC witha grain size distribution of an average crystallite size of 8 nm. Mo¨ ssbauer spectroscopy, AC-susceptibility andmagnetization measurement results indicate that the FCC alloy displays two magnetic behaviors; a paramagneticcomponent that orders along over a wide temperature range below 220 K, and a minor antiferromagnetic fraction thatis still ordered at room temperature. The average hyperfine field (Bhf=5.2 T) and the isomer shift (d=0.07mm/s) valuesat T=23K show that Fe atoms are in a FCC structure that includes Mn and Cu atoms. In addition, we verified thatpresence of Cu stabilizes the FCC-Fe(Mn,Cu) phase.