INVESTIGADORES
DI SALVO Florencia
artículos
Título:
The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: coordinated nitrosyl as an oxidizing agent
Autor/es:
DOCTOROVICH, F, GRANARA, M. AND DI SALVO, F.
Revista:
TRANSITION METAL CHEMISTRY
Editorial:
Kluwer Academic Publishers
Referencias:
Lugar: Netherlands; Año: 2001 vol. 26 p. 505 - 509
ISSN:
0340-4285
Resumen:
[Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenylmethanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are produced as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed.
