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Título:
A complex containing three different kinds of RuN bonds: ethoxydinitronitrosyl(N,N,N',N'-tetramethylethylenediamine-kappa2N,N')ruthenium(II)
Autor/es:
PABLO ALBORES; ZULEMA D. CHAIA; LUIS BARALDO; EDUARDO E. CASTELLANO; OSCAR E. PIRO
Revista:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Editorial:
International Union of Crystallography
Referencias:
Año: 2002 p. 235 - 236
ISSN:
0108-2701
Resumen:
The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2(C6H16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state.
