INVESTIGADORES
MONTSERRAT Javier Marcelo
artículos
Título:
Exploring the use of a guanine-rich catalytic DNA for sulfoxide preparation.
Autor/es:
MARÍA DELLAFIORE; JAVIER MONTSERRAT; ADOLFO IRIBARREN
Revista:
PLOS ONE
Editorial:
PUBLIC LIBRARY SCIENCE
Referencias:
Lugar: San Francisco; Año: 2015 vol. 10 p. 129695 - 129706
ISSN:
1932-6203
Resumen:
A guanine-rich DNA oligonucleotide complexed with heminwas used to catalyze controlled oxygen transfer reactions to different sulfidesfor sulfoxide preparation in the presence of H2O2.Comparable activities were obtained when using fully modified L-DNA. Inaddition, oligonucleotide immobilization led to an active catalyst which couldbe successfully recovered and reused without loss of activity.
