REVERSIBLE BREAKING AND FORMING OF METAL-LIGAND COORDINATION BONDS: TEMPERATURE TRIGGERED SINGLE-CRYSTALTO-SINGLE-CRYSTAL TRANSFORMATION IN A METAL?ORGANIC FRAMEWORK

MARIA C. BERNINI ; FELIPE GANDARA; M. IGLESIAS; N. SNEJKO; E. GUTIERREZ-PUEBLA; E. V. BRUSAU; G.E. NARDA; M.A. MONGE

CHEMISTRY-A EUROPEAN JOURNAL

WILEY-V C H VERLAG GMBH

Lugar: Weinheim; Año: 2009 vol. 15 p. 4896 - 4905

0947-6539

[Yb(C4H4O4)15] undergoes a temperature-triggered single-crystal to single-crystal transformation. Thermal X-ray single-crystal studies showed a reversibly orchestrated rearrangement of the atoms generated by the breaking/formation of coordination bonds, in which the stoichiometry of the compound remains unchanged. The transformation occurs on heating the crystal at «130 °C. This uncommon behavior was also studied by thermal methods, FTIR spectroscopy, and thermodiffrac-tometry. Both polymorphs, a (room-temperature form) and b (high-temperature form), are proven to be active heterogeneous catalysts; the higher catalytic activity of b is owed to a decrease in the Yb coordination number. A mechanism based on spectroscopic evidence and involving formation of the active species Yb-O-OH is proposed for the sulfide oxidation.