TRANSFORMACION QUIMICA Y MICROBIOLOGICA DE GRINDELANOS

CIFUENTE, D.A., CARRIZO FLORES, R.A., TONN, C.E., KURINA SANZ, M.

HUERTA GRANDE, CORDOBA

Simposio; XIII SIMPOSIO NACIONAL DE QUIMICA ORGANICA; 2001

ASPERGILLUS NIGER SP BIOTRANSFORMATES GRINDELANE DERIVATIVES INTO DIFFERENT PRODUCTS ACCORDING TO THE LATERAL CHAIN MOIETIES. STEREO AND REGIOESPECIFIC HYDROXYLATION IN POSITION 3 B WAS OBSERVED ONTO GRINDELIC ACID, MEANWHILE REDUCTIONS AND HYDROXYLATIONS OF METHYL GROUPS WERE CARRIED OUT ON ITS ESTER AND ALCOHOLIC DERIVATIVES