Scaling laws in adsorption on bivariate surfaces.

F. BULNES; A. J. RAMIREZ-PASTOR; G. ZGRABLICH

PHYSICAL REVIEW E - STATISTICAL PHYSICS, PLASMAS, FLUIDS AND RELATED INTERDISCIPLINARY TOPICS

Año: 2002 vol. 65 p. 31603 - 31609

1063-651X

The adsorption of particles with nearest-neighbor attractive and repulsive interactions is studied through Monte Carlo simulation on bivariate surfaces characterized by patches of weak and strong adsorbing sites of size l. Patches are considered to have either a square or a strip geometry and they can be either arranged in a deterministic ordered structure or in a random way. Quantities are identified that scale obeying power laws as a function of the scale length l. The consequences of this finding are discussed for the determination of the energetic topography of the surface from adsorption measurements.l. Patches are considered to have either a square or a strip geometry and they can be either arranged in a deterministic ordered structure or in a random way. Quantities are identified that scale obeying power laws as a function of the scale length l. The consequences of this finding are discussed for the determination of the energetic topography of the surface from adsorption measurements.l. The consequences of this finding are discussed for the determination of the energetic topography of the surface from adsorption measurements.