INVESTIGADORES
GUASTAVINO Javier Fernando
artículos
Título:
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
Autor/es:
GUASTAVINO, JAVIER F.; ROSSI, R. A.
Revista:
ORGANOMETALLICS
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2009 vol. 28 p. 2646 - 2649
ISSN:
0276-7333
Resumen:
The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield
