PERSONAL DE APOYO
PALACIO Magdalena
capítulos de libros
Título:
Ecofrieodly catalysts based 00 mixed xerogels
Autor/es:
M. PALACIO; P. VILLABRILLE; G. ROMANELLI; P. VAZQUEZ; C. CACERES
Libro:
Scientific bases for the preparation of heterogeneous catalysts
Editorial:
Elsevier
Referencias:
Año: 2010; p. 425 - 428
Resumen:
In this study Ti02-CeO2 and Ti02-V2OSmixed oxide were synthesized by sol-gel
technique. The mixed xerogels were prepared with different load of Ti02 and Ce02 or
V2Os,using titanium isopropoxideand hexahydratedceriumnitrate or vanadyl acetylacetonate
as precursors, and ethanol (99.8%) as solvent. The gels were dried in air at 50°C
for 24 h and calcined in air at temperatures in fue range 200-800°C for 4 h. Moreover, a
sample without cerium, 100% (w/w) Ti~, was prepared to be kept as referente
material. The prepared solids were characterized by means ofXRD, FT-IR and TEM.
Their textural properties were determined by adsorption-desorption isotherms of N2 at
77 K. The xerogels were tested as catalysts in fue liquid phase oxidation of 2,6-
dimethylphenol to 2,6-dimethyl-p-benzoquinone at 20°C, using ethanol as solvent and
aqueous hydrogen peroxide as a c1eanoxidizing agent.