INVESTIGADORES
ROMANELLI Gustavo Pablo
artículos
Título:
Phenol and naphthol oxidation to quinones with hydrogen peroxide using vanadium-substituted Keggin heteropolyacid as catalyst
Autor/es:
G. ROMANELLI, P. VILLABRILLE, P. VÁZQUEZ, C. CÁCERES, P. TUNDO
Revista:
LETTERS IN ORGANIC CHEMISTRY
Editorial:
BENTHAM SCIENCE PUBL LTD
Referencias:
Lugar: Bossun; Año: 2008 vol. 5 p. 332 - 335
ISSN:
1570-1786
Resumen:
Phenols and naphthols were oxidized to the corresponding quinones using 60% p/V hydrogen peroxide and a substituted vanadium Keggin heteropolyacid (H4PMo11VO40.12H2O, HPA) as catalyst. The reactions were carried out at room temperature using acetone as solvent. This procedure was a mild and effective alternative for the phenol oxidation to quinones in good yields
