SURFACE INTERMEDIATE SPECIES OF THE 4-ISOBUTYLACETOPHENONE ADSORPTION-REACTION OVER FOSFOTUNGSTIC

SILVANA R. MATKOVIC; GRACIELA M. VALLE; LAURA E. BRIAND

LATIN AMERICAN APPLIED RESEARCH

UNS

Lugar: Bahía Blanca; Año: 2009 p. 173 - 178

0327-0793

Surface adsorbed species of isobutylbenzene and 4-isobutylacetophenone on bulk fosfotungstic Wells-Dawson acid have been screened in the present investigation. The evolution of chemisorbed species towards products was followed through infrared spectroscopy of systems containing liquid reactants and the solid acid kept at various temperatures. Isobutylacetophenone adsorbs on Brønsted acid sites of the heteropoly acid and further reacts towards a condensation product similarly to the reaction of acetophenone over other acid materials such as, mordenite, niobic acid and sulfated zirconia. The condensation product possesses well defined infrared signals at 1654 cm-1 and 1597 cm-1 that resemble the carbonyl stretching vibration and the double bond of dypnone. Additional signals at 1221 cm-1 give more evidences of the formation of a chalcone type compound. A reaction mechanism of the Aldol condensation of 4-isobutylacetophenone through an enol reactive intermediate is proposed.