PHYSICAL PROPERTIES AND PHASE EQUILIBRIA OF THE SYSTEM ISOPROPYL ACETATE + ISOPROPANOL + 1-OCTYL-3-METHYL-IMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

ALFONSINA ESTER ANDREATTA; ALBERTO ARCE; EVA RODIL; ANA SOTO

FLUID PHASE EQUILIBRIA

ELSEVIER SCIENCE BV

Lugar: New York; Año: 2010 vol. 287 p. 84 - 94

0378-3812

Densities, refractive indices and dynamic viscosities of binary and ternary mixtures composed of isopropyl acetate, isopropanol, 1-octyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl) imide ([C8mim][NTf2]) have been determined at 298.15 K and atmospheric pressure. The excess molar volumes and dynamic viscosity changes of mixing have been calculated and correlated using the Redlich-Kister polynomial equation. Isobaric vapour-liquid equilibrium (VLE) data have been determined experimentally for these binary and ternary systems at 101.32 kPa. The equilibrium data have been adequately correlated by means of Wilson, NRTL, and UNIQUAC equations for the liquid phase activity coefficient.