INVESTIGADORES
MOGLIE Yanina Fernanda
artículos
Título:
Copper Nanoparticles Supported on Zinc Oxide as Efficient Catalyst for the N ‐Arylation of (Hetero)cyclic and Acyclic Amides
Autor/es:
MOGLIE, YANINA; MASCARÓ, EVANGELINA; ZACCONI, FLAVIA; RADIVOY, GABRIEL
Revista:
ChemistrySelect
Editorial:
Wiley
Referencias:
Año: 2021 vol. 6 p. 4412 - 4417
ISSN:
2365-6549
Resumen:
Copper nanoparticles (CuNPs) supported on ZnO are highlyactive and selective heterogeneous catalyst for the N-arylationof cyclic and acyclic amides (Golberg coupling). The reactionconditions are mild, featuring K3PO4as a base and N,N?-dimethylethylendiamine (DMEDA) as ligand in refluxing acetonitrile. The CuNPs/ZnO catalyst can be recovered andreused in six cycles with only little loss of activity. Themethodology can be successfully scaled up to gram scalewithout decreasing the catalytic activity.
