INVESTIGADORES
GASNIER Aurelien
artículos
Título:
Acid?Base-Driven Interconversion between a Mononuclear Complex and Supramolecular Coordination Polymers in a Terpyridine-Functionalized Dioxocyclam Ligand.
Autor/es:
AURELIEN GASNIER; JEAN-MICHEL BARBE; CHRISTOPHE BUCHER; FRANCK DENAT; JEAN-CLAUDE MOUTET; ERIC SAINT-AMAN; PIERRE TERECH; GUY ROYAL
Revista:
INORGANIC CHEMISTRY
Editorial:
AMER CHEMICAL SOC
Referencias:
Año: 2008 vol. 47 p. 1862 - 1864
ISSN:
0020-1669
Resumen:
A polytopic cyclam-bis-terpyridine ligand has been used to accomplish an acid?base-triggered formation of either a mononuclear neutral complex or metallopolymers with Cu2+ ions. A controlled interconversion between these two forms was achieved through the reversible displacement of a Cu2+ cation from the macrocycle to the terpyridine units.
