Stability and Activity of Zn/MCM-41 Materials in Toluene Alkylation: Microwave Irradiation vs Continuous Flow

CARRARO, PAOLA M.; GOLDANI, BRUNA S.; ALVES, DIEGO; SATHICQ, A. GABRIEL; EIMER, GRISELDA A.; ROMANELLI, GUSTAVO P.; LUQUE, RAFAEL

Catalysts

MDPI

Lugar: Basilea; Año: 2019 vol. 9

Zn/MCM-41 mesoporous materials have been prepared via classic wet impregnation,employing zinc nitrate as precursor and tested for activity and stability in the Friedel-Crafts alkylation of toluene with benzyl chloride under microwave irradiation and continuous flow. The modified materials were characterized by means of a number of analytical techniques, and surface and textural properties were thoroughly checked. Materials containing the highest Zn loading (15 wt %) provided full conversion after 5 min reaction under microwave irradiation (300 W, 120 ◦C). Materials were proved to be stable and reusable for several cycles with an optimum performance under continuous flow conditions