Kinetics of the formation of the novel peroxide FC(O)OOS(O2)F.

MARIA EUGENIA TUCCERI; BADENES, M. P.; CROCE, A. E.; COBOS, C. J.

Chemical Communications

Año: 2001 vol. 1 p. 71 - 72

1359-7345

The high-pressure rate coefficient for the formation of the new peroxide FC(O)OO(O2)SF from recombination of FC(O)O and FS(O2)O radicals has been determined by laser flash photolysis at 296 K; density functional theory calculations indicate peroxide stabilization and allow estimation ofan O–O bond dissociation energy of 20.6 ± 3 kcal mol.