Characterization of an anionic-exchange membranes for direct methanol alkaline fuel cells

GRACIELA C. ABUIN; PATRICK NONJOLA; ESTEBAN A. FRANCESCHINI; FEDERICO H. IZRAELEVITCH; MKHULU K. MATHE; HORACIO R. CORTI

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

PERGAMON-ELSEVIER SCIENCE LTD

Año: 2010 vol. 35 p. 5849 - 5854

0360-3199

Ammonium quaternized polymers such as poly (arylene ether sulfones) are being developed and studied as candidates of ionomeric materials for application in alkaline fuel cells, due to their low cost and promising electrochemical properties. In this work, a quaternary ammonium polymer was synthesized by chloromethylation of a commercial polysulfone followed by amination process. Quaternized polysulfone membrane properties such us water and water-methanol uptake, electrical conductivity and Young´s modulus were evaluated and compared to Nafion 117, commonly employed in direct methanol fuel cells. The anionic polysulfone membrane sorbs more water than Nafion all over the whole range of water activities, but it uptakes much less methanol as compared to Nafion. The specific conductivity of the fully hydrated polysulfone membrane equilibrated with KOH solutions at ambient temperature increases with the KOH concentration, reaching a maximum of 0.083 S cm−1 for 2 M KOH, slightly less conductive than Nafion 117. The elastic modulus of the polysulfone membranes inmersed in water is similar to that reported for Nafion membranes under the same conditions. We concluded that quaternized polysulfone membrane are good candidates as electrolytes in alkaline direct methanol fuel cells.