INVESTIGADORES
SPANEVELLO Rolando Angel
artículos
Título:
Diels-Alder reaction of two green chiral precursors. Approach to natural product like structures
Autor/es:
CARRAU, G.; VEIGA, N.; SUESCUN, L.; GIRI, G. F.; SUÁREZ, A. G.; SPANEVELLO, R. A.; GONZÁLEZ, D.
Revista:
TETRAHEDRON LETTERS
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2016
ISSN:
0040-4039
Resumen:
Diels?Alder cycloaddition between an enantiomerically pure protected cis-cyclohexadiene diol metabolite and optically pure levoglucosenone derived from cellulose gave rise to complex pentacyclic natural product like structures in a chemically succinct process. The adducts were fully characterized and the observed results were in accord with theoretical calculations performed on the possible course of the reaction.
