INVESTIGADORES
SPANEVELLO Rolando Angel
artículos
Título:
Diels-Alder Reaction of Sugar-Derived Cyclic Dienophiles with Cyclopentadine. Factors Affecting the Reactivity and Stereoselectivity
Autor/es:
PELLEGRINET, S. C.; SPANEVELLO, R. A.
Revista:
ORGANIC LETTERS
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2000 vol. 2 p. 1073 - 1076
ISSN:
1523-7060
Resumen:
A sugar-derived cyclic dienophile showed a high exo and face selectivity in the Diels-Alder reaction with cyclopentadiene. Structural modifications on the dienophile structure were made, and the outcomes of the cycloaddition reactions were investigated. These results and the spectroscopic data recorded within a series of analogues were used to analyze the factors affecting the reactivity and exo selectivity.
