INVESTIGADORES
SPANEVELLO Rolando Angel
artículos
Título:
Microwave-assisted asymmetric Diels-Alder reaction using chiral auxiliaries derived from biomass
Autor/es:
SAROTTI, A. M.; SPANEVELLO, R. A.; SUÁREZ, A. G.
Revista:
Arkivoc
Editorial:
ARKAT-USA
Referencias:
Lugar: Florida; Año: 2010 vol. 2011 p. 31 - 37
ISSN:
1424-6376
Resumen:
Microwave-assisted asymmetric Diels-Alder reactions using levoglucosenone-derived chiral auxiliaries have been investigated. The cycloaddition reaction between the corresponding chiral acrylate and cyclopentadiene showed important rate enhancements under microwave irradiation compared to conventional heating conditions, whereas the yields and diastereoselectivities were not significantly affected.
