INVESTIGADORES
BIANCHI Dario Alejandro
artículos
Título:
A tosyliminium ion-based total synthesis of (±)-schefferine.
Autor/es:
BIANCHI, DARIO A.; KAUFMAN, TEODORO S.
Revista:
CANADIAN JOURNAL OF CHEMISTRY
Editorial:
National Research Council of Canada
Referencias:
Año: 2000 p. 1165 - 1169
ISSN:
0008-4042
Resumen:
The synthesis of the phenolic tetrahydroprotoberberine alkaloid (±)-schefferine is reported, featuring as key steps a tosyliminium ion-mediated Friedel?Crafts alkylation of eugenol dimethyl ether and an intramolecular Mitsunobu-type amination.