INVESTIGADORES
URANGA Jorge Gustavo
artículos
Título:
Using experimental and computational approaches to probe an unusual carbon-carbon bond cleavage observed in the synthesis of benzimidazole N-oxides
Autor/es:
POLITANO, FABRIZIO; LEÓN SANDOVAL, ARTURO; URANGA, JORGE GUSTAVO; BUJAN, ELBA; LEADBEATER, NICHOLAS E.
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2020
ISSN:
1477-0520
Resumen:
Experimental and computational studies have been performed in order to investigate an unusual carbon-carbon bond cleavage that occurs in the preparation of certain benzimidazole N-oxides from anilines. The key factor determining the outcome of the reaction was found to be the substituents on the amine functionality of the aniline.