INVESTIGADORES
URANGA Jorge Gustavo
artículos
Título:
Reactivity of endo-3-bromocamphor with sulfur-centered nucleophiles by an electron transfer mechanism. Electrophilic behaviour of the 3-camphoryl radical
Autor/es:
JORGE G. URANGA Y ANA N. SANTIAGO
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: Cambrigde; Año: 2011 vol. 9 p. 2969 - 2974
ISSN:
1477-0520
Resumen:
The photostimulated reaction of arylthiolate ions with endo-3-bromocamphor produced both reduction and substitution products. The pKa and proton affinities values of the cojugaded acids are good indicators of the reactivity.