Acrylonitrile butadiene nanocomposites containing different clays by latex compounding method

COVA, MARIAJOSE; FERNÁNDEZ, MARIELA; FERNÁNDEZ, ALEJANDRA; GARCÍA, DANIELA; BACIGALUPE, ALEJANDO; TORRES SÁNCHEZ, ROSA MARÍA; ESCOBAR, MARIANO

POLYMER ENGINEERING AND SCIENCE

JOHN WILEY & SONS INC

Año: 2019 vol. 59 p. 736 - 744

0032-3888

Considering elastomers nanocomposites, most of the works are focused on natural rubber, styrene butadiene rubber and rubber blends, while few of them deal with nitrile butadiene rubber (NBR). This article presents the reinforcing effect of two raw sodic montmorillonites (Mts) and one organoclay on NBR matrix prepared by the latex compounding method. Raw Mts increase the mechanical properties of neat matrices. A pseudoplastic behavior is observed with the incorporation of clays into the NBR latex, indicating interactions between polymer chains and clay sheets, in agreement with the results of zeta potential analysis. X-ray diffraction evaluates changes in the interlayer distance of the clay, indicating the NBR intercalation phenomenon in all cases. Matrices with different clay proportions present variations in the mechanical properties, depending if the aggregation phenomenon is promoted. Morphological analysis of clays and nanocomposites as well as thermal analysis were performed. The variation in mechanical properties after an aging process was studied, evaluating the effects on the tensile strength, ultimate strain and 300% modulus. POLYM. ENG. SCI., 59:736?744, 2019. © 2018 Society of Plastics Engineers.