Enhancing Mechanical Properties of Ceramic Papers Loaded Whit Zeolites using Borate Compounds as Binder

JUAN PABLO CECCHINI; RAMIRO M. SERRA; MARÍA ALICIA ULLA; MIGUEL A. ZANUTTINI; VIVIANA G. MILT

BIORESOURCE TECHNOLOGY

ELSEVIER SCI LTD

Lugar: Amsterdam; Año: 2013 vol. 8 p. 313 - 326

0960-8524

NaY zeolite-containing ceramic papers were prepared by a papermaking technique with a dual polyelectrolyte retention system that implied the use of cationic and anionic polumers. To improve their mechanical properties, we found that some borate compounds could be successfully used as ceramic binders. Three types of sodium and/or calcium borates were tested as binders:colemanite, nobleite, and anhydrous ulexite. The improvement in the mechanical properties depends both on the borate used and on the calcination temperature. By XRD it was determined that the faujasite structure collapsed after calcination at 700ºC, which limited the final calcination temperature of zeolitic ceramic papers. Different amounts of NaY zeolite were added to ceramic papers and, as observed by SEM, faujasite particles were well distributed throughout the ceramic paper structure. Ceramic papers containg 1.2 wt.% zeolite after calcination at 650º C resulted in structured catalysts that were wasy-to-handle, and which can be adapted to different conformation.