Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil

BOLDRINI D.; TONETTO G.; DAMIANI D.

CHEMICAL ENGINEERING JOURNAL

ELSEVIER SCIENCE SA

Lugar: Amsterdam; Año: 2015 vol. 270 p. 378 - 384

1385-8947

Partial hydrogenation of sunflower oil was studied over Pd/Al2O3/Al catalysts in a monolithic stirred reactor. The catalyst showed similar or even better activity and selectivity than conventional Pd/Al2O3 catalysts. However, in consecutive runs, a continuous decreasing activity was observed. In order to understand the deactivation phenomena, fresh and spent catalysts were characterized using temperature programmed reduction, N2 adsorption isotherms, dynamic H2 chemisorption, transmission electron microscopy (TEM), atomic absorption spectroscopy, inductively coupled plasma spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy, ultrasound adherence tests, and X-ray photoelectron spectroscopy. Furthermore, an extensive number of catalytic tests under different operating conditions were carried out. The loss in activity was proportional to thereduction in metal dispersion. The decrease in Pd dispersion was due to the coverage of thePd surface. The deactivation occurred due to fouling with reaction residues most probablycoming from polymerization and/or cross-linking reactions. The catalysts can be regenerated ex-situ using a careful desorption-washing-calcination process, although this requires further research because the temperatures required are too high for Al.