INVESTIGADORES
FERNANDEZ LORENZO Monica Alicia
artículos
Título:
Comparative study of oxygen/ozone mixtures on the electrochemical behaviour of different metals
Autor/es:
VIERA, M; FERNÁNDEZ LORENZO DE MELE, M; VIDELA,H
Revista:
JOURNAL OF APPLIED ELECTROCHEMISTRY
Editorial:
SPRINGER
Referencias:
Año: 2001 vol. 31 p. 591 - 598
ISSN:
0021-891X
Resumen:
The effect of dissolved ozone on the electrochemical behaviour of heat
exchanger structural materials (carbon steel, stainless steel, copper,
70:30 copper?nickel, aluminium brass and titanium grade 1) was studied
to evaluate the possibility of using ozone as sole biocide in cooling
water treatment. With this purpose, voltammetric and open circuit
potential (OCP) against time measurements at different ozone
concentrations between 0.1 and 1.2 ppm were made. Results show different
electrochemical responses according to the metal characteristics and
the solution composition. First, the passivity of titanium and stainless
steel was not affected by ozone. A linear OCP against log time
relationship was found for titanium, suggesting the growth of a barrier
film in both O2 and O2/O3 solutions.
Mild steel does not passivate in synthetic cooling water either with O2
or O2/O3 in the solution. In the presence of
ozone the breakdown of passivity is facilitated and makes the
repassivation difficult. Ozone enhances the dissolution of Cu2O
and the formation of Cu(II) species leading to less protective films.
Both processes are strongly influenced by the pH. Finally, the
dissolution of aluminium brass is higher than that of copper or
copper?nickel.