INVESTIGADORES
MARTINO Debora Marcela
congresos y reuniones científicas
Título:
Synthesis and Characterization of styrene-based biopolymers
Autor/es:
D. REYNA; D. A. ESTENOZ; D. M. MARTINO
Lugar:
Montreal
Reunión:
Congreso; 8th World Congress of Chemical Engineering; 2009
Institución organizadora:
WCCE8
Resumen:
A study of bioinspired polymers, similar to polystyrene (PS) and
containing thymine and charged functional groups chemically bonded to the
structure of PS, is presented. These environmentally benign, water-soluble and
non-toxic polymers undergo a photodimerization reaction of the thymine units
when exposed to UV radiation (l~254 nm). The polymers
create crosslinked networks in regions of UV exposure, rendering the polymer
insoluble in those areas. The molecular structure (molecular weight
distribution and chemical composition) and the physical properties (solubility
and photoreactivity) of the thymine-containing polymers are determined by the
synthesis and the curing conditions. Vinylbenzyl thymine (VBT) was
copolymerized with vinylbenzyl triethylammonium chloride (VBA) in a free
radical polymerization (2,2-azobisisobutyronitrile-AIBN). Aqueous solutions of
copolymers were distributed homogeneously on different substrates, irradiated
with 254nm or 520nm using a sensitizer (Eosin Y, lmax=520nm). The crosslink was
monitored in function of irradiation time, light intensity, comonomer ratio,
film thickness and sensitizer concentration using UV-vis and FT-IR.