INVESTIGADORES
MARTIN Sandra Elizabeth
artículos
Título:
Non-linear Chemical Dynamics in the Activation of Haloalkanes by Iron(III)
Autor/es:
MARISA MARTINELLI; SANDRA E. MARTÍN; ANGELA R. SUÁREZ
Revista:
TETRAHEDRON LETTERS
Editorial:
Elsevier Science Ltd.
Referencias:
Año: 2000 vol. 41 p. 6695 - 6699
ISSN:
0040-4039
Resumen:
Catalytic dehydrohalogenation of dihaloalkanes with Fe(III) and its mechanism has been investigated. Damped oscillations of the reaction mixture were observed when the reactions were carried out at 50C in evacuated systems. We have described the main features of this behavior taking into account the organometallic intermediates, the reversibility of the reaction and the catalyst transformation.
