A Closer Insight in to the Mechanism Operating in the Trifluoroacetilation of Pyrrole. New Trifluoromethyl pirrroylmethane Discovered

WALTER J. PELÁEZ; MAXIMILIANO BURGOS; GUSTAVO A. ARGÜELLO.

TETRAHEDRON LETTERS

PERGAMON-ELSEVIER SCIENCE LTD

Año: 2009 vol. 50 p. 1934 - 1938

0040-4039

A former studied reaction of acetylation of pyrrole was revisited and this allowed the identification of new compounds and the isolation and characterization of a very stable solid (2,20,200-(2,2,2-trifluoroethane- 1,1,1-triyl)tris(1H-pyrrole)). All these materials were probably missed, buried in the black tar that characterizes the reaction. A careful and thorough selection of the reaction?s conditions provided both evidence for three new compounds and a closer insight into the mechanism operating at room and lower temperatures.0,200-(2,2,2-trifluoroethane- 1,1,1-triyl)tris(1H-pyrrole)). All these materials were probably missed, buried in the black tar that characterizes the reaction. A careful and thorough selection of the reaction?s conditions provided both evidence for three new compounds and a closer insight into the mechanism operating at room and lower temperatures.H-pyrrole)). All these materials were probably missed, buried in the black tar that characterizes the reaction. A careful and thorough selection of the reaction?s conditions provided both evidence for three new compounds and a closer insight into the mechanism operating at room and lower temperatures.