Effect of leakage currents on the primary current distribution in bipolar electrochemical reactors

HENQUÍN EDUARDO R.; BISANG JOSÉ M.

JOURNAL OF APPLIED ELECTROCHEMISTRY

Springer

Lugar: Dordecht, The Netherlands; Año: 2007 vol. 37 p. 877 - 886

0021-891X

The primary current distribution in a bipolar electrochemical reactor with outside inlet and outlet electrolyte manifolds was investigated by numerical solution of the Laplace equation and by experimental measurement in simulated cells made from conductive paper and segmented electrodes. The geometric parameters determining the distribution were the interelectrode gap, electrode length, transverse section and length of the electrolyte manifold. The effect of the number of electrodes in the bipolar stack was also analysed. Values obtained numerically have been compared with those obtained experimentally and a good agreement is observed between them. These results are useful for estimating the performance of the bipolar stack.