Growth and characterization of single crystal fiber with controlled concentration gradient in GdTaO4-ErTaO4 system

ALMEIDA, R.; TIRAO, G.; C. CUSATIS; ANDRETTA, J. A.

JOURNAL OF CRYSTAL GROWTH

Elsevier Science B.V.

Lugar: HOLANDA; Año: 2006 vol. 294 p. 447 - 451

0022-0248

The LHPG technique has been successfully applied to the growth of single crystals in fiber shape with a controlled composition and lattice parameter gradient along the fiber axis. The GdTaO4–ErTaO4 system was chosen for having a full solubility range. The obtainedfibers had a constant gradient of lattice parameters along the axis with a value of 1.24%/cm for the (44¯ 4) reflection, hence of concentration gradient. Structural characterization results showed that the fibers had a good crystalline quality essential for the optimization of others physical properties. Luminescent characterization showed the behavior of the intensity of green and redluminescence (by 488nm pumping) as a function of concentration of Er3+ and three processes populating the levels (2H11/2, 4S3/2) and 4F9/2 by cross-relaxation energy transfer has been proposed. The results presented show that the compositional gradient and the LHPGtechnique can be used not only for the growth of crystals with controlled lattice parameter gradients, for potential X-ray diffraction applications, but also as a combinatorial method for the rapid study of material properties as a function of concentration using in situ measurements.