Photolysis Rate Coefficients in the Upper Atmosphere: Effect of Line by Line Calculations of the O2 Absorption Cross Section in the Schumann - Runge Bands

RAFAEL PEDRO FERNÁNDEZ; GUSTAVO GERARDO PALANCAR; SASHA MADRONICH; BEATRIZ MARGARITA TOSELLI

JOURNAL OF QUANTITATIVE SPECTROSCOPY AND RADIATIVE TRANSFER

Elsevier

Año: 2007 vol. 104 p. 1 - 11

0022-4073

A line by line (LBL) method to calculate a highly resolved O2 absorption cross section in the Schumann-Runge (SR) bands region was developed and incorporated in the widely used Tropospheric Ultraviolet Visible (TUV) model to calculate accurate photolysis rate coefficients (J values) in the upper atmosphere. In order to obtain the O2 cross section between 49000 cm-1 and 57000 cm‑1, an algorithm which considers the position, strength, and half width of each spectral line was used. Every transition was calculated by using the HIgh-resolution TRANsmission molecular absorption database (HITRAN) and a Voigt profile. The temperature dependence of both the strength and the half widths was considered within the range of temperatures characteristic of the US standard atmosphere, although the results shows a very good agreement also at 79 K. The cross section calculation was carried out on a 0.5 cm-1 grid and the contributions from all the lines lying at ±500 cm-1 were considered for every wavelength. Both, the Schumann-Runge and the Herzberg continuums were included. The J values calculations were performed for altitudes from 0 to 100 km and for solar zenith angles up to 75º. The results show, in the JO2 case, differences of more than 10% (at 97 km of altitude and 30º) when compared against the last version of the TUV model (4.2), which uses the Koppers and Murtagh parameterization. In consequence, the J values of species with cross sections overlapping the SR band region, show variable differences at lower altitudes. Although many species have been analyzed the results for only four of them (O2, N2O, HNO3, CFC113) are presented. Due to the fact that the HNO3 absorption cross section extents up to 350 nm this molecule was used to verify the consistency of the new LBL model at lower altitudes. Thus, it shows differences up to 5.7 % at 20 km but 0 % in the troposphere.