Electrochemical methods to detect susceptibility of Ni-Cr-Mo-W alloy 22 to intergranular corrosion.

GORHE, D D; RAJA, K S; NAMJOSHI, A; VELIMIR RADMILOVIC,; TOLLEY, ALFREDO JUAN; JONES, D A

METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE

TMS

Año: 2005 vol. 36 p. 1153 - 1167

1073-5623

Alloy 22 (UNS N06022), a Ni-Cr-Mo-W based alloy, is a candidate material for the outer wall of nuclear waste package (NWP) containers. Even though the alloy is highly stable at low temperatures, it could undergo microstructural changes during processing such as welding and stress relieving. Formation of topologically close-packed (TCP) phases such as m, P, m, etc. and Cr-rich carbides could make the material susceptible to localized corrosion. Hence, it is important to correlate the microstructural changes with the corrosion resistance of the alloy by nondestructive and rapid electrochemical tests. In this investigation, different electrochemical test solutions were used to quantify the microstructural changes associated with aging and welding of the wrought alloy 22. The results of double-loop (DL) electrochemical potentiodynamic reactivation (EPR) tests in 1 M H2SO4 + 0.5 M NaCl + 0.01 M KSCN solution indicated Cr depletion during initial stages of aging of wrought alloy 22. Results of EPR tests in 2 M HCl + 0.01 M KSCN solution at 60 °C correlated well with the Mo depletion that occurred near TCP phases formed during aging of both weld and wrought alloy 22 materials. The EPR test results were compared with standard chemical weight loss measurements specified by ASTM standard G-28 methods A and B.