INVESTIGADORES
POSTIGO Jose Alberto
artículos
Título:
RADICAL PERFLUOROALKYLATION REACTIONS
Autor/es:
BARATA-VALLEJO, SEBASTIAN; VICTORIA COOKE; A POSTIGO
Revista:
ACS Catalysis
Editorial:
AMERICAN CHEMICAL SOCIETY-10.1021/acscatal.8b02066
Referencias:
Lugar: WASHNGTON; Año: 2018 vol. 8 p. 7287 - 7307
ISSN:
2155-5435
Resumen:
10.1021/acscatal.8b02066Recent protocols and reactions for catalytic radical perfluoroalkylations (RF = CnF2n+1, n 2) will be described. The production of RF radicals that effect both addition and substitution reactions on organic substrates can be realized through a range of diverse methods such as the well-established visible light transition metal-mediated photocatalysis, organic dye-photocatalyzed reactions, by Electron Donor Acceptor (EDA) complexes or more recently through Frustrated Lewis Pairs (FLP). Thus, perfluoroalkylation reactions of carbon-carbon multiple bonds, isocyanides, nitrones, hydrazones, -ketoesters, -cyano arylacetates, sulfides, and (hetero)arenes will be described. Specially emphasis will be made on examples published after 2015 where higher fluorinated series of fluoroalkylating reagents are studied.
