INVESTIGADORES
POSTIGO Jose Alberto
artículos
Título:
Radical Fluoroalkylation Reactions of (Hetero)arenes and Sulfides under Red Light Photocatalysis
Autor/es:
YERIEN, DAMIAN E.; COOKE, MARÍA VICTORIA; GARCÍA VIOR, MARIA CECILIA; BARATA-VALLEJO, SEBASTIAN; POSTIGO, AL
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2019 vol. 17 p. 3741 - 3747
ISSN:
1477-0520
Resumen:
10.1039/C9OB00486FFluoroalkylation reactions of (hetero)aromatics have beenaccomplished through the low-power illumination from red LEDs( lmax= 635 nm) of commercially available perfluoroalkyl iodides RFIand phthalocyanine zinc salt as photocatalyst in MeCN : DMFsolvent mixture. This methodology has been extended to theperfluorobutylation of sulfides. As far as we are concerned, this isthe first report on a perfluoroalkylation reaction of(hetero)aromatics and sulfides under red-light photocatalysis.
