INVESTIGADORES
POSTIGO Jose Alberto
artículos
Título:
Silylation of substituted pyridins
Autor/es:
MARÍA DEL PILAR ARDANZA; BELÉN ETCHEPARRE; AL POSTIGO *
Revista:
Molecular Medicinal Chemistry
Editorial:
INSTITUTO DE INVESTIGACIÓN DE LAS CIENCIAS EXACTAS FÍSICAS Y NATURALES
Referencias:
Lugar: Buenos Aires; Año: 2007 vol. 12 p. 12 - 16
ISSN:
1666-888X
Resumen:
A preliminary study on the reactivity of trimethylsilyconide anion Me3Si- (1) in HMPT (Shippey and Dervan, 1977) on haloaromatic compounds outlined concerns about the reaction mechanism involved, registering a dichotomy between electron-transfer (ET) in box and halogen-metal exchange (HME).