INVESTIGADORES
POSTIGO Jose Alberto
artículos
Título:
RADICAL REACTIONS IN AQUEOUS MEDIUM USING (Me3Si)3SiH
Autor/es:
AL POSTIGO; SERGEY KOPDOV,; CARLA FERRERI,; CHRYSSOSTOMOS CHATGILIALOGLU,
Revista:
ORGANIC LETTERS
Editorial:
American Chemical Society
Referencias:
Lugar: ATLANTA. DOI: 10.1021/ol7020803; Año: 2007 vol. 9 p. 5159 - 5162
ISSN:
1523-7060
Resumen:
(TMS)3SiH was used as a successful reagent in a variety of radical-based transformations in water. The system comprised of substrate, silane, and initiator (ACCN) mixed in aqueous medium at 100 °C worked well for both hydrophilic and hydrophobic substrates, with the only variation that an amphiphilic thiol was also needed in case of the water-soluble compounds.
