INVESTIGADORES
SAROTTI Ariel Marcelo
artículos
Título:
Evaluation of the use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of secondary cyclohexenols
Autor/es:
SAROTTI, A.M.; PISANO, P.L.; PELLEGRINET, S.C.
Revista:
ARKIVOC - ONLINE JOURNAL OF ORGANIC CHEMISTRY
Editorial:
ARKAT USA INC
Referencias:
Año: 2011 p. 343 - 357
ISSN:
1551-7004
Resumen:
The use of mandelate derivatives to determine the enantiomeric purity and the absolute
configuration of isomeric mixtures of bicyclic and monocyclic secondary cyclohexenols was
investigated. Synthesis, NMR and conformational analyses of the derivatives were performed
and Gauge-Independent Atomic Orbital (GIAO) 1H NMR Boltzmann weighted average chemical
shifts were computed. The studied methodology proved to be of practical value for most of the
systems under study.1H NMR Boltzmann weighted average chemical
shifts were computed. The studied methodology proved to be of practical value for most of the
systems under study.