INVESTIGADORES
SAROTTI Ariel Marcelo
artículos
Título:
NMR and experimental reinvestigation of the condensation reaction between γ-methylene- α,β-unsaturated aldehydes and propargyl aldehydes
Autor/es:
RIVEIRA, M. J.*; SAROTTI, A.M.*
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2018
ISSN:
1477-0520
Resumen:
The condensation reaction between a γ-methylene-α,β-unsaturated aldehyde and phenylpropargyl aldehyde was revisited and guided by extensive DFT calculations of NMR shifts. It was found to afford a deconjugative aldol condensation product.Accordingly, a simple protocol for the preparation of valuable cross-conjugated oxatrienes was uncovered.
