Stacked wire-mesh monoliths for VOCs combustion: Effect of the mesh-opening in the catalytic performance

SANZ, OIHANE; BANÚS, EZEQUIEL D.; GOYA, AINTZANE; LARUMBE, HAIZEA; DELGADO, JUAN JOSÉ; MONZÓN, ANTONIO; MONTES, MARIO

CATALYSIS TODAY

ELSEVIER SCIENCE BV

Año: 2017 vol. 296 p. 76 - 83

0920-5861

Structured reactors based on low cost metallic wire-mesh substrates of highly enhanced transport properties can be an interesting alternative to parallel channel monolithic reactors. In this work stacked wire-mesh monoliths were studied for volatile organic compounds elimination. Monoliths of different mesh-opening were homogeneously and adherently dip-coated with Pt/Manganese Octahedral Molecular Sieve (OMS-2) bifunctional catalyst. The catalytic activity was tested in toluene and methanol complete oxidation reactions. Catalytic activity increases using stacked wire-mesh monoliths instead of parallel channel monoliths and decreases when increasing the wire-mesh opening, showing the importance of the mass-transfer phenomena (contact between the gas phase and the solid catalyst).