Comparative study of the effects os aqueous micelar media formed by amphiphilic ionic liquids and conventional surfactants on reactions of synthetical interest

CLAUDIA G. ADAM; CLAUDIA DELLA ROSA, ELISA PAREDES, MARÍA KNEETEMAN, PEDRO M. E. MANCINI; JÉSICA B. SOFFIETTI

Chem. Proc

BASEL SWITSERLAND

Lugar: Basel; Año: 2022 vol. 8 p. 89 - 94

2504-3900

Abstract: For polar Diels?Alder (DA) reactions, one of the most relevant aspects is its dependenceon the reaction media; thus, in this work, the objective is to analyze the effect of aqueous micellarsystems on the synthesis of compounds of biological interest. Based on the system formed by isopreneand 2-nitrofuran, the experiments were carried out in micellar media formed by amphiphilic ionicliquid (N,N-dodecylmethylimidazolium bromide) and by conventional surfactants (SDS and CTAB).In this sense, there are few studies that involve DA reactions in micro-heterogeneous systems. Thechallenge is to have the knowledge about the behavior of ILs in order to take advantage of all theirpotentialities in order to replace a toxic molecular solvent with ILs, which allows the development ofa methodology framed within the concepts of Green Chemistry.