INVESTIGADORES
BUDEN Maria Eugenia
artículos
Título:
Synthesis of g-disubstituted nitroalkyl compounds through a new
Autor/es:
MARÍA E. BUDÉN, SANTIAGO E. VAILLARD, AND ROBERTO A. ROSSI*
Revista:
Arkivoc
Editorial:
ARKAT, USA
Referencias:
Año: 2005 vol. xii p. 163 - 174
ISSN:
1424-6376
Resumen:
The synthesis of g-disubstituted nitroalkanes using alkenes as starting materials is described. The synthetic strategy involves a first step of solvomercuration followed by an SRN1 substitution reaction in DMSO as solvent under photoinitiation. The target compounds are obtained in good yields and the factors governing the distribution of substitution products are discussed.
