Ionic photofragmentation of ClSO2NCO in the S 2p, Cl 2p and S 2s regions.

BETANCOURT ,ANGELICA MORENO, ROMANO, ROSANA M., ERBEN, MAURICIO F., GERONÉS, MARIANA, RODRIGUEZ PIRANI, LUCAS, DELLA VÉDOVA, CARLOS O., AND CAVASSO FILHO, R. L.

Campinas

Congreso; 21ª Reunião Anual de Usuários (RAU), Laboratório Nacional de Luz Síncrotron.; 2011

Laboratorio Nacional de Luz Sincrotrón

On the frame of a general project aimed to the elucidation of the photochemical and electronic properties of molecules containing the XSO2 - group, with X = halogen,1 we present here the study of the electronic properties and the dynamic of the ionic photofragmentation of chlorosulfonyl isocyanate, ClSO2NCO, in the S 2p, Cl 2p and S 2s regions. The Total Ion Yield (TIY), PEPICO and PEPIPICO spectra of ClSO2NCO in vapour phase were recorded.